Journal
CATALYSTS
Volume 7, Issue 12, Pages -Publisher
MDPI
DOI: 10.3390/catal7120354
Keywords
promiscuity; lipase; TEMPO (2,2,6,6-tetramethyl-1-piperidinyloxy); oxidation; salicyl alcohol
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Funding
- Foundation of Graduate Innovation Fund of Jilin University [2016057]
- Changchun BC & HC Pharmaceutical Technology Co., Ltd. [3R116V401465]
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A novel and efficient oxidation of salicyl alcohols to the corresponding salicylaldehydes catalyzed by lipase is reported for the first time. Under the optimal reaction conditions, the method exhibited high yields (81-95%) and selectivities for salicylaldehydes. Moreover, this study expands the application of enzyme catalytic promiscuity in organic synthesis.
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