Journal
CATALYSTS
Volume 7, Issue 3, Pages -Publisher
MDPI
DOI: 10.3390/catal7030086
Keywords
phenols; hydrogenation; Ru nanoparticles; dendrimers; organo-silica materials
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Funding
- Russian Foundation for Basic Research [16-33-60101mol_a_dk]
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New hybrid catalysts based on Ru nanoparticles, encapsulated into poly(propylene imine dendrimers), immobilized into silica pores, were synthesized and examined for the hydrogenation of alkyl-substituted phenols. The corresponding alkyl-substituted cyclohexanols were presented as the major reaction products, while incomplete hydrogenation products appeared to be minor. A competition between the sterical factors of dendrimer-containing carriers and the electronic factors of substrate substituents influenced the hydrogenation rate of the alkyl-substituted phenols. The carrier structure was found to have a significant influence on both the physical and chemical properties of the catalysts and their hydrogenation activity. The synthesized hybrid catalysts appeared to be stable after recycling and could be re-used several times without significant loss of activity.
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