Journal
ENERGY STORAGE MATERIALS
Volume 2, Issue -, Pages 14-20Publisher
ELSEVIER
DOI: 10.1016/j.ensm.2015.11.006
Keywords
Lithium-ion capacitors; Oxygen functional groups; Nanoporous carbons
Funding
- University of Queensland
- University of New South Wales
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Pseudocapacitive storage of monovalent alkali cations, such as Li+ and Na+, is critically important for the development of metal-ion capacitors. Functional carbon materials decorated with ketone-containing groups are excellent candidates for this purpose. An epoxidation approach was deployed in this work to decorate electroactive oxygen groups on a high surface area nanoporous carbon with aligned mesopores. Because of the turbostratic structure, the intermediate epoxides dissipated into double-bonded oxygen groups in the functionalized carbon. The synergy of large porosity, good conductivity and enhanced surface redox activity endows the functionalized carbon cathode with high capacity (313 mA h/g@50 mA/g), good stability ( > 200 cycles) and high rate capability (148 mA h/g@400 mA/g). (C) 2015 Elsevier B.V. All rights reserved.
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