Journal
POLIMERY
Volume 62, Issue 4, Pages 272-282Publisher
INDUSTRIAL CHEMISTRY RESEARCH INST
DOI: 10.14314/polimery.2017.272
Keywords
ring-opening polymerization; gamma-butyrolactone; gamma-butyrolactone derivatives; thermodynamic limitations; homopolymerization of gamma-butyrolactone
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Funding
- Synthesis of well-defined novel copolymers by use of living polymerization methods and advanced chromatography technique [SAS-MOST JRP 2014-9]
- Grant Agency VEGA through project [2/0112/13]
- Slovak Research and Development Agency through grant [APVV-14-0932]
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gamma-Butyrolactone (gamma-BL) derivatives are reviewed from the point of view of their ability to form polymers by ring-opening polymerization. The thermodynamic limitations for polymerization of gamma-BL are discussed. Polymerizability of naturally available unsaturated and synthetic functional gamma-BL derivatives enabling postfunctionalization of final polyesters is presented. Homopolymerization of gamma-BL derivatives with significant effect of the substituent on the gamma-BL ring strain is shown.
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