Journal
NANOSCALE RESEARCH LETTERS
Volume 12, Issue -, Pages -Publisher
SPRINGER
DOI: 10.1186/s11671-017-2377-1
Keywords
Bi4Ti3O12 nanoparticles; Ag3PO4 nanoparticles; Bi4Ti3O12/Ag3PO4 heterojunction; Photocatalytic performance; Photocatalytic mechanism
Funding
- National Natural Science Foundation of China [51662027, 51262018]
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In this work, we integrated Ag3PO4 with Bi4Ti3O12 to form Bi4Ti3O12/Ag3PO4 heterojunction nanocomposites by an ion-exchange method. The as-prepared Bi4Ti3O12/Ag3PO4 composites were systematically characterized by means of XRD, SEM, TEM, BET, XPS, UV-vis DRS, EIS, PL spectroscopy, and photocurrent response. SEM, TEM, and XPS results demonstrate the creation of Bi4Ti3O12/Ag3PO4 heterojunction with obvious interfacial interaction between Bi4Ti3O12 and Ag3PO4. PL spectra, EIS spectra, and photocurrent responses reveal that the composites display an enhanced separation efficiency of photogenerated electron-hole pairs, which is due to the charge transfer between Bi4Ti3O12 and Ag3PO4. Rhodamine B (RhB) was chosen as the target organic pollutant to evaluate its degradation behavior over Bi4Ti3O12/Ag3PO4 composites under simulated sunlight irradiation. Compared to bare Bi4Ti3O12 and Ag3PO4 nanoparticles, the composites exhibit a significantly enhanced photocatalytic activity. The highest photocatalytic activity is observed for the 10% Bi4Ti3O12/Ag3PO4 composite with 10% Bi4Ti3O12 content, which is about 2.6 times higher than that of bare Ag3PO4. The photocatalytic mechanism involved was investigated and discussed in detail.
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