3.8 Article

Mechanical, Dielectric, and Spectroscopic Characteristics of Micro/Nanocellulose plus Oxide Composites

Journal

NANOSCALE RESEARCH LETTERS
Volume 12, Issue -, Pages -

Publisher

SPRINGEROPEN
DOI: 10.1186/s11671-017-1862-x

Keywords

Cellulose; Micro/nanosize; Morphology; Oxide; Composite; Luminescence

Funding

  1. State Fund for Fundamental Research [F64/42-2016, F64/44-2016]
  2. Ministry of Education of Ukraine [16BF051-01]

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The set of composite materials that consist of micro/nanocellulose and complex K2Eu(MoO4)(PO4) luminescent oxide particles was prepared. The composites were studied by means of scanning electron microscopy, XRD analysis, dilatometry, differential scanning calorimetry and thermogravimetric analysis, and dielectric and luminescence spectroscopy. Dependencies of density, crystallinity, relative extension, thermal extension coefficient, dielectric relaxation parameters, intensity and shape of photoluminescence bands on temperature, and content of oxide component were studied. The structure of the composite without oxide is formed by grains of nearly 5 50 mu m in size (crystallinity is about similar to 56%). Structure of the micro/nanocellulose samples which contain oxide particles is similar, but the cellulose grains are deformed by oxide particles. Dependencies of the abovementioned properties on temperature and oxide content were analyzed together with data on the size distribution of oxide particles for the samples for various oxide and molecules of water concentrations.

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