Journal
NANO ENERGY
Volume 34, Issue -, Pages 164-171Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.nanoen.2017.02.022
Keywords
Environmentally-friendly; Chitosan; Electron transport layers; Self-assembly; Organic solar cells
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Funding
- Natural Science Foundation of China [21634004, 51673072, 91633301]
- Ministry of Science and Technology [2014CB643501]
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In this work, we employed chitosan, which is the second most abundant biomass on earth after cellulose, and its derivatives as cathode interlayer (instead of substrate) materials in inverted organic solar cells (OSCs) by employing electrostatic Layer-by-Layer (eLbL) self-assembly technique. It was found that the eLbL self assembly technique was a suitable strategy to obtain continuous films with full surface coverage, uniformity and controlled thickness under nanometer scale. What's more, due to the highly ordered layer-by-layer structure, both interfacial dipoles and molecular dipoles were formed and utilized to decrease the work function of the electrode and enhance device performance. With optimized chitosan eLbL films as cathode interlayer, inverted OSCs exhibited a power conversion efficiency (PCE) of 9.34%, which was approximately a 200% improvement over cells with no cathode interlayer. Moreover, the chitosan eLbL films can be utilized to improve the PCE of thick active layer (210 nm) OSC5 to 10.18%.
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