Journal
NANO ENERGY
Volume 41, Issue -, Pages 109-116Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.nanoen.2017.09.022
Keywords
Self-adaption; Yolk-shell structure; Cobalt sulfide; High performance; Alkali cations storage
Categories
Funding
- National Key Research and Development Program of China [2016YFA0202603]
- National Basic Research Program of China [2013CB934103]
- Programme of Introducing Talents of Discipline to Universities [B17034]
- National Natural Science Foundation of China [51521001]
- National Natural Science Fund for Distinguished Young Scholars [51425204]
- Fundamental Research Funds for the Central Universities [WUT: 2016III001, 2017III009]
- China Scholarship Council [201606955096]
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To address the severe volume changes of transition metal chalcogenides that results in inferior cycling performance, herein, a unique yolk-shell microsphere composed of mesoporous cobalt sulfide yolk and alveolus-like carbon shell (M-CoS@C) is constructed. The mesoporous CoS yolks possess large surface area (46.3 m(2) g(-1)) accompanied with the interconnected mesoporous structure, which provide a large contact area to facilitate the permeation of the electrolyte and shorten the ion diffusion path. The alveolus-like carbon shells provide enough void spaces and highly self-adaptive structure to ensure the high stability of the electrode. Owing to the multi-functionality of this unique structure, the M-CoS@C electrode shows impressive cycling stability (790 mA h g(-1) after 500 cycles at 1 A g(-1) for Li-storage, 532 mA h g(-1) after 100 cycles at 0.2 A g(-1) for Na-storage) and excellent rate capability (330 mA h g(-1) at 20 A g(-1) for Li-storage, 190 mA h g(-1) at 20 A g(-1) for Na-storage). This unique mesoporous yolks@alveolus-like carbon shell structure and the self-sacrificing synthesis method present the effective strategies to promote the utilization of transition metal chalcogenides for practical applications.
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