4.6 Article

The excited-state intramolecular proton transfer properties of three imine-linked two-dimensional porous organic polymers

Journal

JOURNAL OF MATERIALS CHEMISTRY C
Volume 5, Issue 23, Pages 5676-5679

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c7tc00123a

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Funding

  1. National Science Foundation (NSF)
  2. Georgia Tech Facilitating Academic Careers in Engineering and Science (GT-FACES) for a Career Initiation Grant
  3. Ohio State University

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We report the synthesis and excited-state intramolecular proton transfer (ESIPT) properties of three tris(N-salicylideneaniline)-based (TSA) imine-linked porous organic polymers (POPs) containing C-3-symmetric 1,3,5-triarylbenzene (TAB), -tristyrylbenzene (TSB), and -tris(arylethynyl) benzene (TAE) monomer units. The TSA-POPs are fluorescent in the solid-state and responsive to Cu2+ and Pd2+.

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