Journal
JOURNAL OF MATERIALS CHEMISTRY C
Volume 5, Issue 18, Pages 4511-4519Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7tc00508c
Keywords
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Funding
- National Natural Science Foundation of China [21671189]
- Strategic Priority Research Program of the Chinese Academy of Sciences [XDB20000000]
- 973 Program [2014CB932101, 2013CB933200]
- Youth Innovation Promotion Association CAS
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A luminescent Ln-MOF (1) with a combination of exceptionally high thermal, air and chemical stabilities has been synthesized. The multi-stimuli-responsive luminescence of 1 makes it a multifunctional chemosensor for metal ions and small organic molecules, which can selectively detect Cd2+/Mn2+ ions as well as methanol/diethyl ether solvent molecules through turn-on/turn-off effects. Compound 1 can also be utilized as a luminescent probe for diethyl ether vapor and the material can be conveniently reactivated for regeneration.
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