Journal
JOURNAL OF MATERIALS CHEMISTRY C
Volume 5, Issue 31, Pages 7784-7798Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7tc02250f
Keywords
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Funding
- Basque Govt. [IT588-13]
- Spanish Govt. (MINECO/FEDER projects) [CTQ2015-64579-C3-3-P, CTQ2016-80955]
- DST, Govt. of India [SB/S1/IC-13/2014]
- CSIR, Govt. of India [01/2551/12/EMR-II]
- IKERBASQUE, Basque Foundation for Science
- Spanish Ministerio de Economia y Competitividad''
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Four new Ir(III) complexes with the general formula [IrHCl(C<^>N)(PPh3)(2)] containing different conjugated Schiff base ligands (C<^>N) have been synthesized and characterized by H-1, C-13, and P-31 NMR, HRMS, and IR spectra and one of them by single crystal X-ray diffraction. Their photophysical properties in solution and in the solid state have been analyzed and three main practical results have been obtained: (i) a dual fluorescent and phosphorescent emissive complex in solution, (ii) successful acid/base sensing in the solid state and (iii) quantitative CO2 detection. Quantum chemical calculations have been employed to assign the character of the lowest excited states. A plausible explanation for the observed aggregation induced enhanced emission (AIEE) is given, based on the restriction of intramolecular motions due to the effect of intermolecular C-H. . .pi and C-H. . .Cl type interactions upon aggregation.
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