4.6 Article

New push-pull polyene chromophores containing a Michler's base donor and a tricyanofuran acceptor: multicomponent condensation, allopolar isomerism and large optical nonlinearity

Journal

JOURNAL OF MATERIALS CHEMISTRY C
Volume 5, Issue 9, Pages 2230-2234

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c7tc00358g

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Funding

  1. Air Force Office of Scientific Research under Small Business Technology Transfer Research program [FA8650-14-C-5005]
  2. Soluxra LLC
  3. Boeing-Johnson Foundation
  4. China Scholarship Council
  5. University Research Program in Hannam University

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The high chemo-selectivity of bis-aldehydes for condensation with both basic and acidic active methylene compounds facilitates a one-pot, three-component reaction to produce dipolar polyene chromophores as the major products for electro-optics.

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