Journal
CATALYSIS TODAY
Volume 280, Issue -, Pages 45-50Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.cattod.2016.09.001
Keywords
Cellulose; Hydrolytic hydrogenation; Subcritical water; Hypercrosslinked polystyrene; Sorbitol
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The study presents the results of cellulose hydrolytic hydrogenation process in subcritical water in the presence of Ru-containing catalysts based on hypercrosslinked polystyrene (HPS) MN-270 and its functionalized analogues: NH2-HPS (MN-100) and SO3H-HPS (MN-500). It was shown that the replacement of the traditional support (carbon) by HPS increases the yield of the main cellulose conversion products polyols important intermediates for the chemical industry. The catalysts were characterized using transmission electron microscopy (TEM), high resolution TEM, and porosity measurements. Catalytic studies demonstrated that the catalyst containing 1.0% Ru and based on MN-270 is the most active. The total yield of sorbitol and mannitol was 50% on the average at 85% cellulose conversion. (C) 2016 Elsevier B.V. All rights reserved,
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