Journal
JOURNAL OF MATERIALS CHEMISTRY C
Volume 5, Issue 38, Pages 9879-9885Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7tc03641h
Keywords
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Funding
- National Natural Science Foundation of China [21325416, 51673151, 51573140]
- National Fundamental Key Research Program [2013CB834701]
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Mechanoluminescence (ML), a fantastic phenomenon, has attracted increasing attention. However, to date, enumerable bright ML luminogens have been reported based on AIE building blocks. Herein, a new non-AIE unit of triphenylamine, for the first time, is utilized to construct a bright ML luminogen of TPA-1BA. Regardless of the similar molecular structure of TPA-1BA and its analogues TPA-2BA and TPA-3BA, totally different mechanoluminescent activities were observed. Through the careful analyses of their crystal structures, it is found that the non-centrosymmetric molecular arrangement and high lattice stability under mechanical stimulation should be mainly responsible for the ML property of TPA-1BA.
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