Journal
JOURNAL OF MATERIALS CHEMISTRY C
Volume 5, Issue 34, Pages 8875-8882Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7tc03171h
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Funding
- National Natural Science Foundation of China [21376038, 21421005, 21406027, 21576040]
- National Basic Research Program of China [2013CB733702]
- Dalian Agency for Science and Technology [2015R040]
- Fundamental Research Funds for the Central Universities [DUT16RC(4)02]
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A new family of perylene diimide (PDI) arrays, heterologous ones (di-PDI and tri-PDI), were designed and efficiently synthesized by Suzuki cross-coupling reactions using two heterologous PDI monomers with different positions of bay- and ortho-substitution, respectively. The compounds exhibit unique photophysical and electrochemical properties and were successfully applied in non-fullerene organic solar cells with a superior power conversion efficiency of 4.55% for tri-PDI.
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