Journal
JOURNAL OF MATERIALS CHEMISTRY A
Volume 5, Issue 4, Pages 1672-1678Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ta09239j
Keywords
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Funding
- National Natural Science Foundation of China [51373142, 51403176, 51673161]
- Scientific and Technological Innovation Platform of Fujian Province [2014H2006]
- Foundation of NSFC-CNRS-PICS [51511130130, PICS 07002 pour le CNRS]
- National Science and Technology Ministry [2014BAF08B03]
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A valid pathway has been exploited to create a B,N co-doped carbon shell on the surface of TiO2 nanoparticles (TiO2@CNB) as a support of Pt nanoparticles. The shell thickness of TiO2@CNB can be easily controlled by pyrolysis of TiO2@polymer networks. The as-prepared Pt/TiO2@CNB catalyst with a thicker CNB layer of 5.0 +/- 0.5 nm shows improved performance for the oxygen reduction reaction (ORR) with high onset (0.65 V) and half-wave potentials (0.56 V), which are significantly higher than those of commercial Pt/C (20 wt%) catalysts. For the methanol oxidation reaction (MOR), the Pt/TiO2@CNB catalyst with a moderate CNB layer of 3.3 +/- 0.3 nm thickness demonstrates the highest activity and stability compared with that with a CNB thickness of 2.1 +/- 0.3, or 5.0 +/- 0.5 nm, even Pt/C. Our findings indicate that the synergy between Pt nanoparticles and the B, N co-doped carbon shell, as well as the shell thickness plays a key role in improving the electrochemical performances of the Pt/TiO2@CNB composite materials.
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