4.6 Article

Metal-functionalized covalent organic frameworks as precursors of supercapacitive porous N-doped graphene

Journal

JOURNAL OF MATERIALS CHEMISTRY A
Volume 5, Issue 9, Pages 4343-4351

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ta09296a

Keywords

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Funding

  1. EU (FET-OPEN 2D-INK) [648786]
  2. Spanish MINECO [MAT2016-77608-C3-1-P, MAT-2014-56143-R, CTQ-2014-59209-P, FEDER-MAT2012-38318-C03]
  3. Spanish MINECO (Excellence Unit Maria de Maeztu) [MDM-2015-0538]
  4. Generalitat Valenciana (Prometeo Program)
  5. Generalitat Valenciana (ISIC-Nano)
  6. INNCIDE program through Vicerectorat d'lnvestigacio i Politica Cientifica of the University of Valencia
  7. Spanish MECD
  8. EU [FP7/2013-IEF-627386]

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Covalent Organic Frameworks (COFs) based on polyimine with several metal ions (Fe-III, Co-II and Ni-II) adsorbed into their cavities have shown the ability to generate N-doped porous graphene from their pyrolysis under controlled conditions. These highly corrugated and porous graphene sheets exhibit high values of specific capacitance, which make them useful as electrode materials for supercapacitors.

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