Journal
JOURNAL OF MATERIALS CHEMISTRY A
Volume 5, Issue 35, Pages 18518-18526Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7ta06288e
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Funding
- JXTG Nippon Oil & Energy Corporation
- Japan Society for the Promotion of Science (JSPS) [15K18270]
- Frontier Research Base for Global Young Researchers, Osaka University
- Grants-in-Aid for Scientific Research [15K18270, 26220911] Funding Source: KAKEN
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We report a one-pot synthesis of MoOx NPs encapsulated inside hollow silica spheres (MoOx@HSS) which act as an efficient and reusable heterogeneous catalyst in the epoxidation of olefins. A yolk-shell nanostructured MoOx-SiO2 composite, consisting of core MoOx NPs and permeable porous hollow silica spheres, was fabricated via a self-assembly approach using poly(acrylic acid) as an organic template and dodecyltrimethoxysilane as a pore-directing agent. On the basis of comprehensive structural analyses by FE-SEM, TEM, elemental mapping, N-2 physisorption and Mo K-edge XAFS, we show that MoOx NPs of ca. 5.8 nm diameter are encapsulated within hollow silica spheres having randomly arranged mesopores of ca. 2.1 nm diameter, while addition of an excess amount of the pore-directing agent leads to a deformation of the yolk-shell nanostructures. The obtained yolk-shell nanostructured MoOx-SiO2 composite exhibits prominent reusability with a modest catalytic activity in the liquid-phase epoxidation of olefins with TBHP owing to the presence of the protective silica shell, making it an effective heterogeneous catalyst for the transformation of olefins into their corresponding epoxides.
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