Journal
JOURNAL OF MATERIALS CHEMISTRY A
Volume 5, Issue 24, Pages 12379-12384Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7ta02644g
Keywords
-
Funding
- National Natural Science Foundation of China [51471168, 51671087]
- Foundation for Innovative Research Groups of the National Natural Science Foundation of China [51621001]
- Natural Science Foundation of Guangdong Province of China [2016A030312011]
- 985 Project of South China University of Technology
Ask authors/readers for more resources
Electrochemically splitting water to produce clean hydrogen fuel requires high-performance electrocatalysts. Here, we report that ternary transition metal boride Co-Ni-B is an active candidate catalyst for water splitting. The Co-Ni-B nanoparticles were deposited on Ni foam (NF) by a facile electroless plating method. After being properly calcined under an Ar atmosphere, the Co-Ni-B@NF catalyst exhibits a low overpotential along with high stability in alkaline solutions for the oxygen evolution reaction, which is among the best reported levels for non-precious metal catalysts. Furthermore, the properly annealed Co-Ni-B@NF catalyst also shows good activity towards the hydrogen evolution reaction. The potential of Co-Ni-B@NF as a bifunctional catalyst for the overall water splitting was demonstrated, with 10 mA cm(-2) achieved at 1.72 V. The favorable combination of high catalytic activity, facile preparation and low cost makes Co-Ni-B@NF a very promising bifunctional catalyst for electrochemical water splitting.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available