4.6 Article

Nanoscale ion intermixing induced activation of Fe2O3/MnO2 composites for application in lithium ion batteries

Journal

JOURNAL OF MATERIALS CHEMISTRY A
Volume 5, Issue 18, Pages 8510-8518

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c7ta00172j

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Funding

  1. SUG
  2. Tier 1 (AcRF grant MOE Singapore) [M4011528 RG99/15]
  3. Tier 2 (AcRF grant MOE Singapore) [M4020159]
  4. Chinese Natural Science Foundation [60906053, 62174118, 51308050309]

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Herein, we demonstrate a facile method to prepare hollow-structured oxygen-vacancy-rich Fe2O3/MnO2 nanorods. Our results show that oxygen vacancies are induced by nanoscale ion intermixing between Fe and Mn ions during the annealing process. Owing to their unique core-shell hollow nanostructure and the presence of oxygen vacancies, the Fe2O3/MnO2 nanorods show excellent electrochemical performances as an anode material for lithium ion batteries and a reversible capacity higher than 700 mA h g(-1) after 2000 cycles.

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