4.6 Article

Redox-active organic-inorganic hybrid polyoxometalate micelles

Journal

JOURNAL OF MATERIALS CHEMISTRY A
Volume 5, Issue 23, Pages 11577-11581

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c7ta00408g

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Funding

  1. EPSRC Directed Assembly Network
  2. University of Nottingham
  3. Nanoscale and Microscale Research Centre
  4. University of Nottingham's Advanced Molecular Material Research Priority Area
  5. University of Nottingham Interdisciplinary Centre for Analytical Science
  6. DAAD
  7. EPSRC Centre for Doctoral Training in Sustainable Chemistry [EP/L015633/1]
  8. Finnish Cultural Foundation (Suomen Kulttuurirahasto)
  9. Engineering and Physical Sciences Research Council [1649973] Funding Source: researchfish

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A redox-active hybrid organic-inorganic polyoxometalate surfactant showed solvent-dependent self-assembly to form nano-scale architectures. The supramolecular assemblies exhibited contrasting electronic structure and redox activity to their molecular building units, and were found to be stable under electrochemical reduction and reoxidation.

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