4.6 Article

Charge transfer induced polymerization of EDOT confined between 2D titanium carbide layers

Journal

JOURNAL OF MATERIALS CHEMISTRY A
Volume 5, Issue 11, Pages 5260-5265

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c7ta00149e

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Funding

  1. Fluid Interface Reactions, Structures and Transport (FIRST) Center, an Energy Frontier Research Center - U.S. Department of Energy, Office of Science, Basic Energy Sciences
  2. Chinese Scholarship Council (CSC)

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In situ polymerization of 3,4-ethylenedioxythiophene (EDOT) is achieved on the surface of 2D Ti3C2Tx MXene without using any oxidant, resulting in improved lithium ion storage capability of Ti3C2Tx/poly-EDOT hybrids. A combined experimental and theoretical study revealed the mechanism of charge-transfer-induced polymerization of EDOT, which can be extended to other similar polymers.

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