Journal
JOURNAL OF MATERIALS CHEMISTRY A
Volume 5, Issue 24, Pages 12103-12112Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ta10675g
Keywords
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Funding
- Basic Science Research Program [2015R1A2A1A01003474, 2015R1D1A1A01057004]
- Wearable Platform Materials Technology Center through the National Research Foundation of Korea (NRF) - Ministry of Science, ICT and Future Planning [2016R1A5A1009926]
- Korea Forest Research Institute [FP 0400-2016-01]
- Development Program of the Korea Institute of Energy Research (KIER) [B6-2431]
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A longstanding challenge facing energy conversion/storage materials is their low electrical conductivity, which often results in unwanted sluggish electrochemical reactions. Here, we demonstrate a new class of one-pot surface engineering strategy based on metallic single-walled carbon nanotube (mSWCNT)-enriched, ivy-like conductive nanonets (mSC nanonets). The mSC nanonets are formed on the surface of electrode materials through a poly(9,9-di-n-octylfluorenyl-2,7-diyl) (PFO)-assisted sonication/filtration process. PFO is known as a dispersant for SWCNTs that shows a higher affinity for semiconducting SWCNTs (sSWCNTs) than for mSWCNTs. Driven by this preferential affinity of PFO, sSWCNTs are separated from mSWCNTs in the form of sSWCNT/PFO hybrids, and the resulting enriched mSWCNTs are uniformly deposited on electrode materials in the form of ivy-like nanonets. Various electrode materials, including lithium-ion battery cathodes/anodes and perovskite catalysts, are chosen to explore the feasibility of the proposed concept. Due to their ivy-like conductive network, the mSC nanonets increase the electronic conductivity of the electrode materials without hindering their ionic transport, eventually enabling significant improvements in their redox reaction rates, charge/discharge cyclability, and bifunctional electrocatalytic activities. These exceptional physicochemical advantages of the mSC nanonets, in conjunction with the simplicity/versatility of the one-pot surface engineering process, offer a new and facile route to develop advanced electrode materials with faster electrochemical reaction kinetics.
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