Journal
JOURNAL OF MATERIALS CHEMISTRY A
Volume 5, Issue 43, Pages 22697-22707Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7ta07654a
Keywords
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Funding
- National Natural Science Foundation of China [51533004, 51473101, 51673135, 21576173]
- Youth Foundation of Science & Technology Department of Sichuan Province [2017JQ0017]
- Programme of Introducing Talents of Discipline to Universities [B13040]
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Structuring nacre-mimetic superstructures during polymer melt processing could be a promising route to high performance structural materials with exceptional strength and toughness. A nacre-mimetic superstructure characterized with aligned lamellae (stiff phase) glued by amorphous polymer chains (soft and tough phase) was fabricated from a biodegradable polymer of poly(butylene succinate) (PBS) with favorable kinetics of crystallization by using an intense shear flow and promoted by natural ramie fiber. The well-aligned layered structure with a thickness of similar to 90 nm for the stiff phase and similar to 100 nm for the soft phase was identified with field-emission scanning electron microscopy, and the nacre-mimetic superstructure was quantitatively characterized by space-resolved small angle X-ray scattering. The thicknesses of crystalline lamellae and the amorphous phase layer between crystalline lamellae in the aligned layers were quantitatively assessed to be 3-4 nm and 4-6 nm respectively, indicating that multilayered crystal stacks are formed in the stiff phase. The nacre-mimetic superstructure leads to highly effective load transfer between the stiff phase and soft phase. Thus, the nacre-mimetic superstructure in PBS and the PBS/ramie fiber biocomposite shows simultaneous enhancement in strength and toughness in comparison to common materials without aligned layered structures. Our findings highlight the significance of nacre-mimetic superstructures in polymeric materials and provide novel prospects for the structuring of polymeric materials during melt processing.
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