4.7 Article

3D cuboidal vanadium diselenide embedded reduced graphene oxide hybrid structures with enhanced supercapacitor properties

Journal

CHEMICAL COMMUNICATIONS
Volume 53, Issue 1, Pages 228-231

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc08035a

Keywords

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Funding

  1. Department of Science and Technology (DST), SERB, Govt. of India [SR/S1/IC-04/2012]
  2. DST (Government of India) [SR/S2/RJN-21/2012]
  3. DST-SERB [SB/FTP/PS065/2013]
  4. UGC-UKIERI [UGC-2013-14/005]
  5. BRNS-DAE [37(3)/14/48/2014-BRNS/1502]
  6. Indo-US Science and Technology Forum (IUSSTF)
  7. Ministry of Human Resources Development (MHRD), India

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The electrochemical supercapacitor performance of a VSe2-reduced graphene oxide (RGO) hybrid has been reported for the first time. The hybrid was synthesized via a one-step hydrothermal route at different concentrations of graphene oxide, i.e. 0.15, 0.3, and 0.75 wt%. Enhanced supercapacitor performances were observed in the case of the hybrid obtained at 0.3 wt% of GO. It showed a specific capacitance of similar to 680 F g(-1) at a mass normalised current of 1 A g(-1) which was similar to 6 and similar to 5 fold higher than those of bare VSe2 and bare RGO, respectively. Furthermore, a high energy density of similar to 212 W h kg(-1), power density of similar to 3.3 kW kg(-1), and similar to 81% retention of the initial capacitance even after 10000 cycles of charge-discharge were observed.

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