Journal
CHEMICAL COMMUNICATIONS
Volume 53, Issue 2, Pages 384-387Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc08318h
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Funding
- Saudi Aramco-KAIST CO2 Management Center
- National Research Foundation of Korea (NRF) - Korea Government (MSIP) [NRF-2015R1A2A2A01004196]
- Korean Ministry of Science, ICT & Future Planning [NRF-2014M1A8A1049254]
- MSIP
- POSTECH
- [IBS-R004-D1]
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Rh(0)/Rh(III) core-shell nanoparticles were prepared by surface oxidation of Rh nanoparticles with N-bromosuccinimide. They were employed as heterogeneous catalysts for cyclic carbonate synthesis from propylene oxide and CO2, and exhibited high activity and excellent recyclability due to Lewis acidic Rh(III) species on the shells.
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