Biowaste-derived substances as a tool for obtaining magnet-sensitive materials for environmental applications in wastewater treatments

In this study, bio-based substances (BBS) obtained from composted urban biowaste are used as stabilizers for the synthesis of magnet-sensitive nanoparticles (NPs). The BBS-stabilized NPs are characterized by means of different techniques (FTIR, XRD, SEM, BET analysis, magnetization curves). Additionally, TGA coupled on-line with FTIR and GC/MS analysis of the exhausted gas are performed in order to simultaneously identify all the degradation products and evaluate the exact composition of such BBS-stabilized materials. Moreover, Fenton-like or photo-Fenton-like experiments carried out at circumneutral pH are performed in order to,evaluate the BBS-functionalized NPs photo-activity towards the degradation of caffeine (taken as model emerging pollutant). The obtained promising results encourage the use of BBS as a green alternative tool for the preparation of smart materials with enhanced magnet-sensitive properties, also suitable for applications in wastewater purification treatments. (C) 2016 Elsevier B.V. All rights reserved.