Journal
CHEMICAL COMMUNICATIONS
Volume 53, Issue 3, Pages 493-508Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc07925c
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Funding
- French National Research Agency [ANR-11-IDEX-0003-02]
- French National Research Agency (CHARMMMAT) [ANR-11-LABX-0039]
- French National Research Agency (INTER-NIT) [ANR-15-CE29-0014-01]
- Ministere de l'Enseignement Superieur et de la Recherche
- Institut de Chimie des Substances Naturelles
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The significant progress made in the area of transition metal-catalyzed nitrene transfer into C-H or C = C bonds mediated by iodine(III) oxidants has been translated into many elegant synthetic applications. This feature article summarizes the main total syntheses that take advantage of such reactions, thereby highlighting that catalytic C(sp(3))-H amination and alkene aziridination reactions have carved out their place in the organic chemist's toolbox.
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