Journal
CHEMISTRY LETTERS
Volume 46, Issue 1, Pages 68-70Publisher
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.160875
Keywords
Carbon dioxide (CO2); N-Methylation; Trimethylamine synthesis
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Funding
- ENEOS Hydrogen Trust Fund
- Japan Society for the Promotion of Science (JSPS) [JP26289299, JP16H06595]
- Ministry of Education, Culture, Sports, Science and Technology of Japan (MEXT)
- Grants-in-Aid for Scientific Research [16H06595, 26289299] Funding Source: KAKEN
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Direct synthesis of trimethylamine through N-methylation of NH3 or its surrogate (NH4HCO3) with both CO2 and H-2 has been achieved by employing Pt and MoOx coloaded TiO2 (Pt-MoOx/TiO2). Pt-MoOx/TiO2 was found to be superior to other supported Pt and transition-metal-loaded MoOx/TiO2 catalysts for the trimethylamine synthesis process.
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