Journal
CERAMICS INTERNATIONAL
Volume 43, Issue 2, Pages 2441-2447Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.ceramint.2016.11.038
Keywords
Precursors: Organic; Composites; Thermal conductivity; Coating
Categories
Funding
- Technology Innovation Program (Development of Integrated Circuit Implementation PPS Composite and 3D Modular Technology for Automotive Electronics) - Ministry of Trade, Industry & Energy (MI, Korea) [10052903]
- Korea Evaluation Institute of Industrial Technology (KEIT) [10052903] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
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In this study, thermally conductive composite was fabricated using hexagonal and spherically aggregated boron nitride filler based on epoxy and polyphenylene sulfide (PPS) matrixes. The spherically aggregated BN (A-BN) particles were shown the outstanding thermal conductivity compared hexagonal BN (H-BN) in the epoxy matrix. However, A-BN is very weak to external forces and broken during PPS based melt processing, causing it to lose the advantage of its particulate shape. Therefore, we adopted a particle coating method for the A-BN to enhance its durability, using pre-ceramic polysilazane (PSZ) in solution. With the PSZ coating of A-BN, the spherical particle shape was retained after melt mixing. Moreover, the interfacial affinity between BN and PPS was enhanced by secondary interactions between the polar functional groups comprising PSZ, thereby increasing the through-plane thermal conductivity from 1.82 to 3.9 W m(-1) K-1 at 70 wt% of A-BN filler, because the spherical filler particles formed a three-dimensional heat flow path.
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