4.7 Article

Quantitative hole collection for photoelectrochemical water oxidation with CuWO4

Journal

CHEMICAL COMMUNICATIONS
Volume 53, Issue 7, Pages 1285-1288

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc09029j

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Funding

  1. National Science Foundation [CHE-1150378]
  2. Direct For Mathematical & Physical Scien
  3. Division Of Chemistry [1150378] Funding Source: National Science Foundation

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The hole collection efficiency of water oxidation was evaluated for CuWO4 electrodes from comparisons of the photocurrent of H2O2 and Na2SO3 oxidation as well as intensity modulated photocurrent spectroscopy (IMPS) measurements. We found current multiplication using H2O2, however use of Na2SO3 and IMPS revealed quantitative water oxidation at 1.23 V vs. RHE.

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