Effect of Mn2+ substitution on structural, electrical transport and dielectric properties of Mg-Zn ferrites

Here we have investigated the effect of Mn2+ substitution on the structural, electrical transport and dielectric properties of Mg-Zn ferrite having chemical formula MnxMg0.5-xZn0.5Fe2O4 (0.005 <= x <= 0.30) synthesized by an oxalate precursor chemical method. X-ray diffraction study reveals the formation of single cubic structure with spinel lattice symmetry without secondary phases having the crystallite size in the range from similar to 25.35-30.36 nm. The Mn2+ substitution leads to the expansion of spinel lattice unit cell of Mg-Zn ferrite system as evidenced from the increase of lattice constant (a) with respect to Mn2+ content. Decrease in the d.c. electrical resistivity as a function of temperature confirms the semiconducting nature of the Mn2+ substituted Mg-Zn ferrite; which is attributed to the Verwey hopping mechanism between Fe2+ double left right arrow Fe3+ ions and Mn2+ double left right arrow Mn3+ The frequency (100 Hz-1 MHz) dependence dielectric properties viz. dielectric constant and dielectric loss measurement shows the usual dielectric dispersion in accordance with the Maxwell-Wagner type interfacial polarization. The a.c. resistivity measurement (100 Hz-1 MHz) suggests the small polaron hopping type conduction is present in the Mn2+ substituted Mg-Zn ferrite system.