Journal
CHEMICAL COMMUNICATIONS
Volume 53, Issue 8, Pages 1348-1365Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc05702k
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Funding
- Royal Society
- EPSRC [EP/L011514/1]
- ERC
- EPSRC [EP/L011514/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/L011514/1] Funding Source: researchfish
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The preparation and applications of heterobimetallic complexes continue to occupy researchers in the fields of organometallic, main group, and coordination chemistry. This interest stems from the promise these complexes hold as precursors to materials, reagents in synthesis and as new catalysis. Here we survey and organise the state-of-the-art understanding of the TM-H-M linkage (M = Mg, Zn, Al, Ga). We discuss the structure and bonding in these complexes, their known reactivity, and their largely unrealised potential in catalysis.
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