Journal
CHEMICAL COMMUNICATIONS
Volume 53, Issue 9, Pages 1478-1481Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc08640c
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Funding
- Board of Research in Nuclear Sciences (BRNS), Government of India [37(2)/14/49/2014-BRNS/]
- CSIR, New Delhi
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A mild, general, and high yielding synthesis of N-acyl 2-aminobenzothiazoles has been demonstrated by N-heterocyclic carbene (NHC)-organocatalyzed direct amidation of aldehydes with 2-aminobenzothiazoles proceeding via acyl azolium intermediates. The carbene generated from the triazolium salt under oxidative conditions was the key for the success of this reaction. The method was subsequently applied to the synthesis of various biologically important N-acyl 2-aminobenzothiazoles.
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