Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 56, Issue 6, Pages 1539-1543Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201611314
Keywords
allenes; borylation; copper; formate esters; silylation
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Funding
- JSPS [25708017]
- JSPS from MEXT, Japan [JP16H01020]
- Grants-in-Aid for Scientific Research [25708017, 25110002, 16H01020, 17H03096, 16H00834, 16H00965] Funding Source: KAKEN
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The boraformylation of allenes with B-2(pin)(2) and a formate ester as boron and formyl source, respectively, proceeds in the presence of a copper catalyst. The reaction selectively affords the corresponding -boryl ,-unsaturated aldehydes in good to high yields. Furthermore, the silaformylation of allenes was achieved with a formate ester and PhMe2Si-B(pin) as the silicon source.
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