Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 56, Issue 7, Pages 1890-1893Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201609077
Keywords
carbon dioxide; cobalt; homogeneous catalysis; hydrogenation; methanol
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Funding
- Mecklenburg-Vorpommern
- BMBF
- CHEM21
- Danish National Research Foundation CADIAC ( Carbon Dioxide Activation Centre)
- BMWi Project Metha-Cycle [Forderkennzeichen: 03ET6071A]
- Ramon Areces Foundation
- LIKAT
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Herein we describe the first homogeneous non-noble metal catalyst for the hydrogenation of CO2 to methanol. The catalyst is formed in situ from [Co(acac)(3)], Triphos, and HNTf2 and enables the reaction to be performed at 100 degrees C without a decrease in activity. Kinetic studies suggest an inner-sphere mechanism, and in situ NMR and MS experiments reveal the formation of the active catalyst through slow removal of the acetylacetonate ligands.
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