Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 56, Issue 7, Pages 1859-1863Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201611705
Keywords
Buchner reaction; carbenes; carbenoids; cyclopropanation; gold
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Funding
- MINECO [CTQ2013-42106-P, SEV2013-0319]
- European Research Council [321066]
- AGAUR [2014 SGR 818]
- Swiss National Science Foundation
- CERCA Programme/Generalitat de Catalunya
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Chloromethylgold(I) complexes of phosphine, phosphite, and N-heterocyclic carbene ligands are easily synthesized by reaction of trimethylsilyldiazomethane with the corresponding gold chloride precursors. Activation of these gold(I) carbenoids with a variety of chloride scavengers promotes reactivity typical of metallocarbenes in solution, namely homocoupling to ethylene, olefin cyclopropanation, and Buchner ring expansion of benzene.
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