Journal
DALTON TRANSACTIONS
Volume 46, Issue 2, Pages 410-419Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6dt04059d
Keywords
-
Categories
Funding
- National Nature Science Foundation of China [21161006, 51569008]
- Nature Science Foundation of Guangxi Province of China [2015GXNSFAA139031, 2015GXNSFAA139240]
- Program for the scientific research and technology development plan of Guilin [20150133-5]
- Guangxi Scientific Experiment Center of Mining, Metallurgy and Environment [KH2012ZD004]
Ask authors/readers for more resources
Four coordination polymers, formulated as [Zn(L-1)(2)](n) (1), [Cd(L-1)(2)](n) (2), [Zn(L-2)(2)](n) (3) and [Cd(L-2)(2)](n) (4) (HL1 is (E)-2-(((4H-1,2,4-triazol-4-yl) imino) methyl)-4,6-dibromophenol; HL2 is (E)-2-(((4H-1,2,4-triazol-4-yl) imino) methyl)-4,6-dichlorophenol) have been synthesized through vial reactions. The four compounds were structurally characterized by single crystal X-ray diffraction, elemental analysis, PXRD, and fluorescence spectroscopy. For 1-4, a detailed analysis of Hirshfeld surfaces and fingerprint plots facilitates a comparison of intermolecular interactions, which are crucial in building different supramolecular architectures. C-H center dot center dot center dot X (X = Br, Cl) interactions play a crucial role in stabilizing the self-assembly process among adjacent 2-D networks for both complexes. Above all, complexes 1-4 showed highly intense electrochemical luminescence (ECL) in DMF solution and high thermal stability.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available