Journal
CHEMICAL SOCIETY REVIEWS
Volume 46, Issue 1, Pages 7-20Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cs00174b
Keywords
-
Categories
Funding
- R. C. Fuson endowment at the University of Nevada, Reno
Ask authors/readers for more resources
Kekulenes, cycloarenes, and heterocycloarenes have attracted much attention though the years, largely due to their electronic structure. The synthesis and characterization of these interesting molecules showed that their pi electrons remained delocalized in individual benzenoid-type rings rather than globally delocalized in an annulenoid fashion. This discovery further suggested that the Clar bonding model, not the Kekule model, is the best representation for depicting the bonding of large macrocyclic aromatic compounds. A plethora of computational studies suggest that cycloarenes gain little, if any, energetic stabilization from global delocalization, obviating the need for the concept of superaromaticity. More recently, cycloarenes have been suggested to serve as models for defects in graphene. Further study into this interesting set of compounds will continue to provide insights into fundamental questions about how aromatic compounds behave.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available