Journal
CARBOHYDRATE POLYMERS
Volume 157, Issue -, Pages 1419-1425Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.carbpol.2016.11.025
Keywords
Cellulose nanofibers (CNFs); Coefficients of thermal expansion (CTE); Epoxy resin; Polyethylenimine (PEI); Nanocomposites; Interfacial enhancement
Categories
Funding
- National Natural Science Foundation of China [51303112, 51473100, 51433006]
- Excellent Young Scholar Fund of Sichuan University [2015SCU04A26]
- State Key Laboratory of Polymer Materials Engineering [sklpme2016-3-09]
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Cellulose nanofibers (CNFs) were surface -modified with polyethyleneimine (PEI), which brought plentiful amine groups on the surface of CNFs, leading to a reduced hydrogen bond density between CNFs and consequently less CNFs agglomerates. The amine groups could also react with the epoxy as an effective curing agent that could increase the interfacial crosslinking density and strengthen interfacial adhesion. The tensile strength and Young's modulus of CNFs-PEI/Epoxy nanocomposites were 88.1% and 237.6% higher than those of neat epoxy, respectively. The tensile storage modulus of the nanocomposites also increased significantly at the temperature either below or above the Tg. The coefficient of thermal expansion for the CNFs-PEI/Epoxy nanocomposites was 22.2 ppm K-1, much lower than that of the neat epoxy (88.6 ppm K-1). In addition, the thermal conductivity of the nanocomposites was observed to increase as well. The exceptional and balanced properties may provide the nanocomposites promising applications in automotive, construction and electronic devices. (C) 2016 Elsevier Ltd. All rights reserved.
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