Journal
CHEMICAL COMMUNICATIONS
Volume 53, Issue 12, Pages 2040-2043Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc10076g
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A new simple protocol, using TMSNTf2 or Tf2NH as the catalyst, for the activation of trichloroacetimidate donors is described. This O-glycosylation proceeds with stereospecific inversion of the donor configuration. The scope of the protocol has been investigated using common glycosyl donors reacting with simple alcohols as well as sugar acceptors.
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