Journal
CORROSION SCIENCE
Volume 115, Issue -, Pages 68-77Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.corsci.2016.11.010
Keywords
Copper; Organic coatings; XPS; Oxidation; Oxide coatings
Funding
- Engineering and Physical Sciences Research Council, UK (EPSRC) and BP plc [EP/J501876/1]
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The behaviour and molecular structure of three organic additives adsorbed from oil onto a copper surface rich in copper (II) oxide is presented. The variation in the ability of these three agents to prevent corrosion of the copper oxide surface by exposure to sulphur is also included. A combination of visible observations, X-ray photoelectron spectroscopy (XPS) and neutron reflection (NR) are used to characterise both the adsorbed layer and underlying copper oxide. The model additives are chosen to represent 'effective', 'intermediate' and 'ineffective' inhibitors for copper. (C) 2016 The Authors. Published by Elsevier Ltd. This is an open access article under the CC BY license (http://creativecommons.orgflicenses/by/4.0/).
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