4.7 Article

Homoleptic organolanthanide compounds supported by the bis(dimethylsilyl)benzyl ligand

Journal

CHEMICAL COMMUNICATIONS
Volume 53, Issue 4, Pages 716-719

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc09304c

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Funding

  1. U.S. Department of Energy, Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences, and Biosciences
  2. U.S. Department of Energy [DE-AC02-07CH11358]

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A beta-SiH functionalized benzyl anion [C(SiHMe2)(2)Ph](-) is obtained by deprotonation of HC(SiHMe2)(2)Ph with KCH2Ph or by reaction of KOtBu and (Me2HSi)(3)CPh; LnI(3)(THF)(n) and three equivalents of this carbanion combine to provide homoleptic tris(alkyl) lanthanide compounds Ln{C(SiHMe2)(2)Ph}(3) (Ln = La, Ce, Pr, Nd) containing secondary metal-ligand interactions.

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