Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 56, Issue 9, Pages 2435-2439Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201610047
Keywords
amines; fluorine; nickel; reaction mechanisms; synthetic methods
Categories
Funding
- JSPS [21245028, A16H02276, 16KT0057, 25708018]
- ACT-C, JST
- Grants-in-Aid for Scientific Research [21245028, 25708018, 16KT0057] Funding Source: KAKEN
Ask authors/readers for more resources
In the presence of Ni-0/PCy3, styrene was found to participate in oxidative cyclization with tetrafluoroethylene, thus leading to the corresponding nickelacycle with a unique (3)--benzyl structure. In addition, the flexibility of the coordination mode in the (3)-benzyl moiety allowed the partially fluorinated nickelacycle to undergo unprecedented amine-induced -fluorine elimination, thus leading to the construction of a fluorinated cyclobutyl skeleton.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available
Share Paper
