Journal
ACS APPLIED MATERIALS & INTERFACES
Volume 9, Issue 7, Pages 5982-5991Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acsami.6b14127
Keywords
double metal phosphide; hollow structure; quasi-polyhedron; ZIF-67; hydrogen evolution reaction; alkaline solution
Funding
- National Natural Science Foundation of China (NSFC) [21475035, 21235002, 21275041]
- Foundation for Innovative Research Groups of NSFC [21521063]
- Program for Changjiang Scholars and Innovative Research Team [IRT1238]
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Double metal phosphide (NiCoP) with hollow quasi -polyhedron structure was prepared by acidic etching and precipitation of ZIF-67 polyhedra and further phosphorization treatment with NaH2PO2. The morphology and microstructure of NiCoP quasi -polyhedron and its precursors were investigated by scanning electron microscopy, transmission electron microscopy, X-ray diffraction, and a micropore and chemisorption analyzer. Electrocatalytic properties were examined by typical electrochemical methods, such as linear sweep voltammetry, cyclic voltammetry, chronoamperometry, and electrochemical impedance spectroscopy in 1.0 M KOH aqueous solution. Results reveal that, compared with CoP hollow polyhedra, NiCoP hollow quasi-polyhedra exhibit better electrochemical properties for hydrogen evolution with a low onset overpotential of 74 mV and a small Tafel slope of 42 mV dec(-1). When the current density is 10 mA cm(-2), the corresponding overpotential is merely 124 my, and 93% of its electrocatalytic activity can be maintained for 12 h. This indicates that NiCoP with hollow quasi -polyhedron structure, bimetallic merit, and low cost may be a good candidate as electrocatalyst in the practical application of hydrogen evolution.
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