4.7 Article

Self-assembly of stable luminescent lanthanide supramolecular M4L6 cages with sensing properties toward nitroaromatics

Journal

CHEMICAL COMMUNICATIONS
Volume 53, Issue 16, Pages 2459-2462

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cc00189d

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Funding

  1. Strategic Priority Research Program of the Chinese Academy of Sciences [XDB20000000]
  2. National Natural Science Foundation of China [21521061, 21402201, 21471150, 21601183]
  3. Natural Science Foundation of Fujian Province [2016J06005, 2016J05051]
  4. Recruitment Program of Global Youth Experts

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We report here the first example of concentration-triggered helicate-to-tetrahedron transformation in supramolecular lanthanide edifices, along with their highly efficient and selective luminescence sensing properties toward PA at the ppb level.

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