Journal
APPLIED SURFACE SCIENCE
Volume 396, Issue -, Pages 672-680Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.apsusc.2016.11.007
Keywords
Nitrene; Azide; Insertion; Polyethylene; Photografting; Perfluorinated compounds
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Funding
- Commission for Technology and Innovation (KTI/CTI), Switzerland
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The purpose of this study is to render polyethylene surfaces strongly and permanently hydrophobic. Polyethylene is a common plastic and, because of its inertness, difficult to graft. We chose polyethylene as example because of its ubiquity and model character. As graft chains linear perfluoroalkyl residues (-C4F9, -C6F13, -C8F17 and -C10F21) were chosen, and photografting was selected as grafting method. Photolytically generated nitrenes can insert into carbon-hydrogen bonds and are therefore suited for binding to polyethylene. Hydrophobic photo reactive surface modifiers based on azide/nitrene chemistry are designed, synthesized in high yield and characterized. Four new molecules are described. Water contact angles exceeding 110 degrees were achieved on grafted polyethylene. One problem is to demonstrate that the photografted surface modifiers are bound covalently to the polyethylene. Abrasion tests show that all new molecules, when photografted to polyethylene, have a higher abrasion resistance than a polyethylene surface coated with a long-chain perfluoroalkane. Relative abrasion resitances of 1.4, 2.0, 2.1 and 2.5 compared to the fluoroalkane coating were obtained for the four compounds. An abrasion model using ice is developed. Although all four compounds have the same lambda max of 266 nm in acetonitrile solution, their molar extincition coefficients increase from 1.6.10(4) to 2.2.10(4) with increasing length of the fluorotelomer chain. Exitonic coupling of the chromophores of the surface modifiers is observed for specific molecules in the neat state. A linear correlation of water contact angle with fluorine surface content, as measured by photoelectron spectroscopy, in grafted polyethylene surfaces is established. (C) 2016 Elsevier B.V. All rights reserved.
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