Journal
DALTON TRANSACTIONS
Volume 46, Issue 8, Pages 2439-2444Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6dt04513h
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Funding
- Royal Society
- Engineering and Physical Sciences Research Council [1290656] Funding Source: researchfish
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A straightforward method for the hydrophenoxylation of internal alkynes, using N-heterocyclic carbenebased copper(I) and gold(I) complexes, is described. The heterobimetallic catalytic system proceeds via dual activation of the substrates to afford the desired vinylether derivatives. This methodology is shown to be highly efficient and tolerates a wide range of substituted phenols and alkynes.
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