Journal
CHEMICAL COMMUNICATIONS
Volume 53, Issue 17, Pages 2598-2601Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc10005h
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Funding
- Basic Science Research Program through the NRF of Korea [2016R1E1A1A01941074]
- Ministry of Science, ICT and Future Planning
- Ministry of Education [2016R1A6A3A11931661]
- National Research Foundation of Korea [2016R1E1A1A01941074] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
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Cu2O nanocubes were used for the synthesis of hollow and microporous Fe porphyrin networks (H-MFePN). In this synthesis, Cu2O nanocubes performed not only as networking catalysts but also as shape controlling templates. MFePNwere formed on the surface of the Cu2O nanocubes through azide-alkyne cycloaddition of tetrakis(4-ethynylphenyl) Fe-porphyrin with 1,4-diazidobenzene. H-MFePN showed excellent catalytic activities in carbene insertion into N-H bonds, maintaining their activities during five recycle tests.
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