Journal
CHEMISTRYOPEN
Volume 6, Issue 2, Pages 247-253Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/open.201600152
Keywords
diphosphoramidites; hydroformylation; regioselectivity; rhodium; structure-activity relationships
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Funding
- Evonik Industries AG
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A series of diphosphoramidites has been synthetized with a piperazine, homopiperazine, and an acyclic 1,2-diamine unit in the backbone. New compounds were tested alongside related N-acyl phosphoramidites as ligands in the Rh-catalyzed hydroformylation of n-octenes to investigate their influence on the activity and regioselectivity. A subsequent study of their hydrolysis stability revealed that the most stable ligands induced the highest activity in the catalytic reaction.
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